Publications (total of >50 beginning in 1969)

BY DR. DALE SHELLHAMER (1988 - PRESENT)

“Correlation of Calculated Halonium Ion Structures with Experimental Product Distributions from Terminal Alkenes: The Effect of Electron-Withdrawing Fluorine Substituents on the Structure and Charge Localization of Halonium Ions,” D.F. Shellhamer, D.C. Gleason*, V.L. Heasley, and J.J. Lehman.  Manuscript in preparation.

“Ionic Reaction of Halogens with Terminal Alkenes: The Effect of Electron-Withdrawing Fluorine Substituents on the Bonding of Halonium Ions,” D.F. Shellhamer, J.L. Allen*, R.D. Allen*, D.C. Gleason*, C. O’Neil Schlosser*, B.J. Powers*, J.W. Probst*, M.C. Rhodes*, A.J. Ryan*, P.K. Titterington*, G.G. Vaughan* and V.L. Heasley.  J. Org. Chem., 68, 3932, 2003.

“Symmetry of Chloronium Ions from Ionic Reactions of Chlorine, Chlorine Monofluoride Gas and Chlorine Monofluoride Complex with Terminal Alkenes,” D.F. Shellhamer, P.K. Titterington*, V.L. Heasley.  J. Fluorine Chem., 124, 17, 2003.

“Comparison of the Electrophilic and Free-Radical Addition of Halogens with Hexafluoro-1,3-butadiene and 1,3-Butadiene,” D.F. Shellhamer, D.C. Gleason*, G.G. Vaughan*, A.J. Ryan*, P.K. Titterington*, V.L. Heasley and J.J. Lehman.  J. Fluorine Chem., 123, 171, 2003.

"Electrophilic vs Free Radical Reactions of Halogens and Halogen Systems with Perfluoroalkenes and a Perfluoroalkylethylene," D.F. Shellhamer, J.L. Allen, R.D. Allen, M.J. Bostic, E.A. Miller, C.M. O'Neill, B.J. Powers, E.A. Price, J.W. Probst, and V.L. Heasley. Journal of Fluorine Chemistry, 2000, 4392, 1-10.

"Generating Interhalogen Fluorides under Mild Conditions: A Comparison of Sluggish and Reactive Interhalogen Fluorides," D.F. Shellhamer, M.J. Horney, B.J. Pettus, T.L. Pettus, J.M. Stringer, and V.L. Heasley. J. Org. Chem., 64, 1999, 1094.

"A Mild Method for introducing iodine Monofluoride into alkenes and Iodination of Aromatics Using Xenon Difluoride," D.F. Shellhamer, B.C. Jones, B.J. Pettus, T.L. Pettus, J.M. Stringer, and V.L. Heasley. J. Fluorine Chem., 88, 1998, 37.

"Facile Addition of Poorly Nucleophilic Alcohols to Unactivated Alkenes." D.F. Shellhamer, R.P. Callahan, V.L. Heasley, M.L. Druelinger and R.D. Chapman. Synthesis, 1997, 9, 1056.

"Addition Reactions of Alkenes with Electronegativley Substituted Alcohols in the Presence of Xenon Difluoride." M.L. Druelinger, D.F. Shellhamer, R.D. Chapman, S.A. Shackelford, M.E. Riner, S.L. Carter, R.A. Callahan, and C.R. Youngstrom. J. Chem. Soc. Perkin Trans 2, 1997, 787.

"Reaction of Aminosulfur Trifluourides with Alcohols: Inversion vs. Retention." D.F. Shellhamer, A.A. Briggs, B.M. Miller, J.M. Prince, D.H. Scott, and V.L. Heasley.J. Chem. Soc. Perkin Trans 2, 1996, 973.

"Effect of Pyridine on the Regio- and Stereo-Chemistry in the Addition of Bromine Chloride to Alpha, Beta-Unsaturated Aldehydes and Ketones." V.L. Heasley, D.S. Elias, P.E. Erdman, D. VanHorn, P.M. Whitelaw and D.F. Shellhamer. J. Chem. Soc. Perkin Trans 2, 1996, 761.

"Reaction of Diethylaminosulfur Trifluoride with Diols." D.F. Shellhamer, D.T. Anstine, K.M. Gallego, B.R. Ganesh, A.A. Hanson, K.A. Hanson, R.D. Henderson, J.M. Prince and V.L. Heasley. J. Chem. Soc. Perkin Trans 2, 1995, 861.

"The Fluorination of Cyclopentadiene and 3,4-Epoxycyclopentene." D.F. Shellhamer, M.C. Chiaco, K.M. Gallego, W.S.C. Low, B. Carter, V.L. Heasley and R.D. Chapman. J. Fluorine Chem., 1995, 72, 83-87.

"Reaction of Alkylhypochlorites and Xenon Difluoride with Cyclohexene." D.F. Shellhamer, M.J. Horney, A.L. Toth and V.L. Heasley.Tetrahedron Letters, 1992, 33, 6903.

"Addition of Iodine Electrophiles to Buta-1,3-Diene: Effects of Charge Distribution and Ion-Pair Stability on Product Ratios." V.L. Heasley, L.S. Holstein, R.J. Moreland, J.W. Rosbrugh and D.F. Shellhamer. J. Chem. Soc. Perkin Trans 2, 1991, 1271.

"Reaction of Xenon Difluoride with Indene in Aqueous 1,2-Dimethoxyethane and Tetrahydrofuran." D.F. Shellhamer, D.L. Carter, M.C. Chiaco, T.E. Harris, R.D. Henderson, W.S.C. Low, B.T. Metcalf, M.C. Willis, V.L. Heasley and R.D. Chapman. J. Chem. Soc. Perkin Trans 2, 1991, 401.

"Chlorination of Alpha, Beta-Unsaturated Ketones and Esters in the Presence of Acid Scavengers." V.L. Heasley, S.L. Elliott, P.E. Erdman, D.E. Figueroa, K.W. Krosley, T.L. Louie, H.B. Moore, B.P. Mudge, D.F. Nogales, J. Nordeen, M.L. Oakes, J.W. Rosbrugh, A.M. Sauerbrey, T.Y. Shibuya, M.S. Stanley, C.C. Stewart, D.F. Shellhamer and G.E. Heasley. J. Chem. Soc. Perkin Trans 2, 1991, 393.

"Specificity of the Hepatocyte Na^+-Dependent Taurocholate Transporter: Influence of Side Chain Length and Charge." Reprinted from HEPATOLOGY, 1991, 13, 1, 68-72. W.G.M. Hardison, V.L. Heasley, D.F. Shellhamer.

"The Regioselectivity in the Addition Reactions of Alkoxyxenon Fluorides with Indene." D.F. Shellhamer, S.L. Carter, R.H. Dunham, S.N. Graham, M.P. Spitsbergen and V.L. Heasley; R.D. Chapman and M.L. Druelinger. J. Chem. Soc. Perkin Trans 2, 1989, 159.

"An Overview of Perfluorocytlbromide Application as a Synthetic Oxygen Carrier and Imaging Agent for X-Ray, Ultrasound and Nuclear Magnetic Resonance." D.M. Long, D.C. Long, R.F. Mattrey, R.A. Long, A.R. Burgan, W.C. Herrick and D.F. Shellhamer. Biomaterials, Artificial Cells and Artificial Organs, 1988, 16 (1-3), 411.